Thermodynamic re-assessment of the ternary system Al-Cr-Ni.

Citation
N. Dupin et al., Thermodynamic re-assessment of the ternary system Al-Cr-Ni., CALPHAD, 25(2), 2001, pp. 279-298
Citations number
43
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
ISSN journal
03645916 → ACNP
Volume
25
Issue
2
Year of publication
2001
Pages
279 - 298
Database
ISI
SICI code
0364-5916(200106)25:2<279:TROTTS>2.0.ZU;2-A
Abstract
A re-assessment of the ternary system AI-Cr-Ni following Dupin's thesis wor k using a single Gibbs energy function for the gamma and gamma' phases is p resented taking into account new experimental liquidus temperatures. The di sordered bcc A2 and ordered B2 phases are also modelled with a single equat ion. The existence of vacancies as defects in this structure is described. The other phases are modelled as substitutional solutions, or as stoichiome tric or non-stroichiometric binary compounds. The present assessment is lim ited to the sub system AlNi-Cr-Ni where no ternary phase exists. The parame ters describing the Gibbs energy of all the assessed phases are given. Exte nsive comparisons between calculation and experimental data are presented.