Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterisations of [Cu-7(OH)(6)Cl-2(pn)(6)(H2O)(2)](C(CN)(3))(4)Cl-2 (pn=1,3-diaminopropane)

Authors
Triki, S Thetiot, F Pala, JS Golhen, S Clemente-Juan, JM Gomez-Garcia, CJ Coronado, E
Citation
S. Triki et al., Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterisations of [Cu-7(OH)(6)Cl-2(pn)(6)(H2O)(2)](C(CN)(3))(4)Cl-2 (pn=1,3-diaminopropane), CHEM COMMUN, (21), 2001, pp. 2172-2173
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
21
Year of publication
2001
Pages
2172 - 2173
Database
ISI
SICI code
1359-7345(2001):21<2172:HHCCOT>2.0.ZU;2-9
Abstract
A new polynuclear copper(II) complex [Cu-7(OH)(6)Cl-2-(pn)(6)(H2O)(2)](C(CN )(3))(4)Cl-2 with hydroxo-bridging ligands has been prepared; the centrosym metric cluster cation can be described as two Cu4O3Cl distorted cubane unit s sharing one copper cation.