Formation and reactivity of a cobalt(II) hydroperoxide intermediate

Authors
Thyagarajan, S Incarvito, CD Rheingold, AL Theopold, KH
Citation
S. Thyagarajan et al., Formation and reactivity of a cobalt(II) hydroperoxide intermediate, CHEM COMMUN, (21), 2001, pp. 2198-2199
Citations number
39
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
21
Year of publication
2001
Pages
2198 - 2199
Database
ISI
SICI code
1359-7345(2001):21<2198:FAROAC>2.0.ZU;2-Y
Abstract
Reaction of Tp(t-Bu,Me)Co-H with O-2 proceeds via a spectroscopically obser vable hydroperoxide whose reactivity in solution and in the solid state dif fer dramatically.