Efficient and selective catalytic oxidative cleavage of alpha-hydroxy ketones using vanadium-based HPA and dioxygen

Authors
El Aakel, L Launay, F Atlamsani, A Bregeault, JM
Citation
L. El Aakel et al., Efficient and selective catalytic oxidative cleavage of alpha-hydroxy ketones using vanadium-based HPA and dioxygen, CHEM COMMUN, (21), 2001, pp. 2218-2219
Citations number
21
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
21
Year of publication
2001
Pages
2218 - 2219
Database
ISI
SICI code
1359-7345(2001):21<2218:EASCOC>2.0.ZU;2-5
Abstract
The combination of H3+n[PMo12-nVnO40]. aq (HPA- n, n = 3) and dioxygen prov ides a clean and regioselective reagent for the homolytic cleavage of vario us representative a hydroxy ketones (primary to tertiary) and turns out to be as efficient for the catalytic ring opening of chiral natural products.