Catalytic C-F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions

Authors
Braun, T Perutz, RN Sladek, MI
Citation
T. Braun et al., Catalytic C-F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions, CHEM COMMUN, (21), 2001, pp. 2254-2255
Citations number
24
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
21
Year of publication
2001
Pages
2254 - 2255
Database
ISI
SICI code
1359-7345(2001):21<2254:CCAOPP>2.0.ZU;2-9
Abstract
The cross-coupling reaction of pentafluoropyridine with tributyl( vinyl) ti n affording 2-vinyltetrafluoropyridine by activation of a carbon-fluorine b ond is catalysed by [NiF( 2-C5NF4)( PEt3)(2)]; a similar reaction is observ ed with 2,3,5,6- tetrafluoropyridine.