Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex

Citation
S. Grundemann et al., Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex, CHEM COMMUN, (21), 2001, pp. 2274-2275
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
21
Year of publication
2001
Pages
2274 - 2275
Database
ISI
SICI code
1359-7345(2001):21<2274:ABIACC>2.0.ZU;2-K
Abstract
2-Pyridylmethylimidazolium salts and IrH5(PPh3)(2) give an [(N-C) IrH2(PPh3 )(2)](+) species with the imidazole ring bound in the 'wrong way': at C-5, not at the expected C-2.