(eta(5)-cyclopentadienyl)(kappa(3)-hydrotris(pyrazolyl)borate)cobalt(II) -the first high-spin cobalt organometallic complex

Authors
Brunker, TJ Barlow, S O'Hare, D
Citation
Tj. Brunker et al., (eta(5)-cyclopentadienyl)(kappa(3)-hydrotris(pyrazolyl)borate)cobalt(II) -the first high-spin cobalt organometallic complex, CHEM COMMUN, (20), 2001, pp. 2052-2053
Citations number
17
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
20
Year of publication
2001
Pages
2052 - 2053
Database
ISI
SICI code
1359-7345(2001):20<2052:(->2.0.ZU;2-S
Abstract
(eta (5)-Cyclopentadienyl)(kappa (3)-hydrotris(pyrazolyl)borate)cobalt(II) has been synthesised; magnetic and crystallographic data indicate this to b e the first example of a high-spin cobalt organometallic complex whilst its pentamethylcyclopentadienyl analogue is found to have a low-spin electroni c configuration.