Alkane oxidation by a carboxylate-bridged dimanganese(III) complex

Authors
Blay, G Fernandez, I Gimenez, T Pedro, JR Ruiz, R Pardo, E Lloret, F Munoz, MC
Citation
G. Blay et al., Alkane oxidation by a carboxylate-bridged dimanganese(III) complex, CHEM COMMUN, (20), 2001, pp. 2102-2103
Citations number
19
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
20
Year of publication
2001
Pages
2102 - 2103
Database
ISI
SICI code
1359-7345(2001):20<2102:AOBACD>2.0.ZU;2-C
Abstract
A new manganese( III) oxamato dimer possesing an unprecedented Mn-2(mu -O2C R)(mu -OH2. . .O2CR) core has been synthesised, structurally and magnetical ly characterised, and used as a catalyst for the oxidation of alkanes to al cohols and ketones by (BuO2H)-O-t and O-2 in CH2Cl2 at rt.