A new pathway in the reaction of disilene with carbonyl compounds: an 'ene' reaction instead of cycloaddition

Authors
Lee, VY Ichinohe, M Sekiguchi, A
Citation
Vy. Lee et al., A new pathway in the reaction of disilene with carbonyl compounds: an 'ene' reaction instead of cycloaddition, CHEM COMMUN, (20), 2001, pp. 2146-2147
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
20
Year of publication
2001
Pages
2146 - 2147
Database
ISI
SICI code
1359-7345(2001):20<2146:ANPITR>2.0.ZU;2-D
Abstract
The 3H-disilagermirene, ((Bu2MeSi)-Bu-t)(4)GeSi2, reacts with a hydrogen co ntaining carbonyl compounds (acetophenone, butane-2,3-dione) by an 'ene'-re action pathway followed by isomerization or insertion reactions, representi ng a new mode in the reaction of disilenes with carbonyl compounds.