Revision of the absolute configuration of the tricyclic sesquiterpene (+)-kelsoene by chemical correlation and enantiospecific total synthesis of itsenantiomer

Authors
Fietz-Razavian, S Schulz, S Diz, I Jones, PG
Citation
S. Fietz-razavian et al., Revision of the absolute configuration of the tricyclic sesquiterpene (+)-kelsoene by chemical correlation and enantiospecific total synthesis of itsenantiomer, CHEM COMMUN, (20), 2001, pp. 2154-2155
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
20
Year of publication
2001
Pages
2154 - 2155
Database
ISI
SICI code
1359-7345(2001):20<2154:ROTACO>2.0.ZU;2-1
Abstract
The absolute configuration of the recently identified sesquiterpene (+)- ke lsoene was revised by chemical correlation with (R)-(+)- pulegone; the corr ect structure is (1R, 2S, 5R, 6R, 7R, 8S)- 2,8-dimethyl-6-(1-methylethenyl) tricyclo[ 5.3.0.0(2,5)]decane.