Assignment of the CK-shell photoabsorption spectrum of CF3CN molecule

Authors
Okada, K Tanimoto, S Ibuki, T Saito, K Gejo, T
Citation
K. Okada et al., Assignment of the CK-shell photoabsorption spectrum of CF3CN molecule, CHEM LETT, (10), 2001, pp. 1046-1047
Citations number
19
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
10
Year of publication
2001
Pages
1046 - 1047
Database
ISI
SICI code
0366-7022(20011005):10<1046:AOTCPS>2.0.ZU;2-Z
Abstract
Assignment of the total C photoabsorption spectrum of CF3CN in the K-shell region has been established with the help of an angle-resolved photofragmen t ion spectroscopy. The anisotropy parameters for the energetic CF3+ and CN + fragments were evaluated at the selected photon energies. The linear C-C= N skeleton basically held in this region since the strongly negative anisot ropy parameters were obtained at the pi (CN)*<--C-F(1s) transition.