Laser pulses can reach such high intensities nowadays that atoms exposed to
them ionize virtually instantaneously. The extracted electrons are then ac
celerated to velocities non-negligible to the speed of light. What remains
are multiply charged ions with their most loosely bound outer electrons equ
ally undergoing relativistic dynamics. These may temporarily escape from th
e vicinity of the ionic core, extract relativistic energies from the laser
field and later recollide with the ionic core. The extremely large energies
exchanged may be emitted in the form of coherent high-frequency light whic
h is beneficial when an upconversion of frequencies is requested. Signature
s of the magnetic field component of the laser field, the relativistic mass
shift and spin-orbit coupling characterize the quantum relativistic dynami
cs. The existence of more than one active electron within the ion and that
of more than one atom in gases or solids complicate the theoretical underst
anding considerably but simple pictures are often possible to a reasonable
approximation.