Absorption of water vapor in a liquid film is an important process in
a proposed solar cooling system. Film absorption involves simultaneous
heat and mass transfer in the gas-liquid system. The heat of absorpti
on gives rise to temperature gradients leading to the transfer of heat
while temperature affects the vapor pressure-composition equilibrium
at the interface between the two phases which in turn influences mass
transfer. The composition of the gas phase, in which a non-absorbable
gas is combined with the absorbate, also influences the combined heat
and mass transfer. The non-absorbable gas, in conjunction with the abs
orbate, is transported by convection and diffusion toward the liquid-g
as interface. Since the interface is impermeable to the non-absorbable
gas, the concentration of the non-absorbable gas at the interface is
significantly greater than that in the bulk of the gas resulting in a
reduction in absorbate mass transfer. An experimental program has been
utilized to study this non-absorbable gas effect on the combined heat
and mass transfer in film absorption. As expected from numerous previ
ously reported studies, the experimental results indicate that signifi
cant increases in the heat and mass transfer rates can be obtained by
reducing the non-absorbable gas concentration to levels approaching 0%
. The Sherwood number and film Nusselt number are correlated using the
film Reynolds number, Prandtl number, Schmidt number, Lewis number an
d air concentration. These effects are shown to have similar trends wh
en compared to a numerical solution of the smooth falling film problem
in which the absorbent and absorbate flow concurrently. (C) 1997 Else
vier Science Ltd.