CRYSTAL-STRUCTURE AND OXO-TRANSFER PROPERTIES OF [NH4](2)[W(VI)O2(O2CC(S)PH(2))(2)]

Authors
CERVILLA A LLOPIS E RIBERA A DOMENECH A SINN E
Citation
A. Cervilla et al., CRYSTAL-STRUCTURE AND OXO-TRANSFER PROPERTIES OF [NH4](2)[W(VI)O2(O2CC(S)PH(2))(2)], Journal of the Chemical Society. Dalton transactions, (23), 1994, pp. 3511-3513
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
23
Year of publication
1994
Pages
3511 - 3513
Database
ISI
SICI code
0300-9246(1994):23<3511:CAOPO[>2.0.ZU;2-N
Abstract
The complex [NH4](2)[(WO2)-O-VI{O2CC(S)Ph(2)}(2)] is the first example of a non-dithiolene tungsten complex capable of oxidising benzoin to benzil in methanol; the reduced complex product formed, presumably a m onomeric (WO)-O-IV species, was reoxidised with nitrate ions, regenera ting the starting (WO2)-O-VI complex which then acts as a true homogen eous catalyst.