Mononuclear chelating diselenito complexes of platinum(II) and the crystalstructure of bis-triphenylphosphine(diselenito-O, O ') platinum(II) - Preference for hard versus soft ligands of the cis-Pt(PPh3)(2) moiety?

Authors
Battan, L Manassero, M Pasini, A
Citation
L. Battan et al., Mononuclear chelating diselenito complexes of platinum(II) and the crystalstructure of bis-triphenylphosphine(diselenito-O, O ') platinum(II) - Preference for hard versus soft ligands of the cis-Pt(PPh3)(2) moiety?, INORG CH C, 4(11), 2001, pp. 606-609
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
11
Year of publication
2001
Pages
606 - 609
Database
ISI
SICI code
1387-7003(200111)4:11<606:MCDCOP>2.0.ZU;2-G
Abstract
An OO' chelating diselenito is found in the X-ray structure of [Pt(PPh3)(2) (Se2O5)]. The possible preference of the cis-Pt(PPh3)(2) moiety towards O, rather than softer donor ligand atoms, is briefly discussed on the basis of other examples. (C) 2001 Elsevier Science B.V. All rights reserved.