A novel one-dimensional oxalato-bridged copper(II) complex with 2,2 '-bipyridine

Authors
Castillo, O Luque, A Iglesias, S Guzman-Miralles, C Roman, P
Citation
O. Castillo et al., A novel one-dimensional oxalato-bridged copper(II) complex with 2,2 '-bipyridine, INORG CH C, 4(11), 2001, pp. 640-642
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
11
Year of publication
2001
Pages
640 - 642
Database
ISI
SICI code
1387-7003(200111)4:11<640:ANOOCC>2.0.ZU;2-U
Abstract
The crystal structure of the compound {[Cu(ox)(bpy)].2.5H(2)O}(n) 1 (ox = o xalate dianion, bpy = 2,2'-bipyridine) consists of columnar stacks of neutr al [Cu(ox)(bpy)] units linked by semicoordination Cu-O bonds. The magnetic properties show the occurrence of alternating ferro-antiferromagnetic inter actions (J(AF) = -2.1cm(-1) and J(F) = +0.2 cm(-1)). (C) 2001 Elsevier Scie nce B.V. All rights reserved.