Photoinduced denitrosyl dinuclearizing reaction of dinitrosyl-molybdenum [Mo(didentate-N,S)(2)(NO)(2)] complexes

Authors
Yonemura, T Nakata, J Kadota, M Hasegawa, M Okamoto, K Ama, T Kawaguchi, H Yasui, T
Citation
T. Yonemura et al., Photoinduced denitrosyl dinuclearizing reaction of dinitrosyl-molybdenum [Mo(didentate-N,S)(2)(NO)(2)] complexes, INORG CH C, 4(11), 2001, pp. 661-663
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
11
Year of publication
2001
Pages
661 - 663
Database
ISI
SICI code
1387-7003(200111)4:11<661:PDDROD>2.0.ZU;2-P
Abstract
The cis(NO,NO)-trans(S,S)-[MoL2(NO)(2)] complexes [L = 2-pyrimidinethiolate (pymt) 1 and 2-pyridinethiolate (pyt) 2] were newly prepared by the reacti on of the [Mo(NO)(2)](2+) solution with the thiolate ligands. Under room li ght, complexes 1 and 2 released one of two nitric oxide (NO) to give mu -OH dinuclear complexes. [{(ON)MoL2}(2)(mu -OH)(2)] (L = pymt 3 and pyt 4). Th e central molybdenum ion circumference turns from six-coordination into sev en-coordination, and oxidation number also varies with this reaction from O to +II. (C) 2001 Elsevier Science B.V. All rights reserved.