Microemulsions as reaction media for a hydrolysis reaction

Citation
Kk. Ghosh et Lk. Tiwary, Microemulsions as reaction media for a hydrolysis reaction, J DISP SCI, 22(4), 2001, pp. 343-348
Citations number
31
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
ISSN journal
01932691 → ACNP
Volume
22
Issue
4
Year of publication
2001
Pages
343 - 348
Database
ISI
SICI code
0193-2691(2001)22:4<343:MARMFA>2.0.ZU;2-1
Abstract
The kinetics of the acidic hydrolysis of N-hydroxyphthalimide (phthalomohyd roxamic acid) have been studied in microemulsions of three components (Aero sol OT (AOT)/isooctane/water) at 328 K. The effect of significant parameter s such as water/AOT mole ratio (omega) and AOT concentration were analyzed. The reaction rate is higher in microemulsions than in conventional aqueous solution. In all cases pseudo first-order kinetics were observed. Activati on parameters have been obtained from the temperature dependence of the rat e constant in the microemulsion.