Co-Al-O film was fabricated using the reactive r.f. magnetron sputtering te
chnique. A maximum magnetoresistance (MR) of approximately 7% was establish
ed through optimizing the sputter deposition conditions such as sputter pow
er and gas flow rate. TEM characterization of the film revealed a nano-gran
ular structure that consisted of ferromagnetic grains with grain diameters
on the order of several nm together with non-magnetic grain boundary layers
with the thickness on the order of less than 1 nm. The large MR was attrib
uted to electron tunneling thorough this very thin grain boundary layer bet
ween individual ferromagnetic grains. (C) 2001 Kluwer Academic Publishers.