Supramolecular complexation of [60]fullerene with hexahomotrioxacalix[3]naphthalenes: a new class of naphthalene-based calixarenes

Authors
Mizyed, S Ashram, M Miller, DO Georghiou, PE
Citation
S. Mizyed et al., Supramolecular complexation of [60]fullerene with hexahomotrioxacalix[3]naphthalenes: a new class of naphthalene-based calixarenes, J CHEM S P2, (10), 2001, pp. 1916-1919
Citations number
34
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
ISSN journal
1472779X → ACNP
Issue
10
Year of publication
2001
Pages
1916 - 1919
Database
ISI
SICI code
1472-779X(200110):10<1916:SCO[WH>2.0.ZU;2-9
Abstract
The hexahomotrioxacalix[3]naphthalenes 4 and 5 which are members of a new c lass of inherently chiral naphthalene-based calixarenes were evaluated for their supramolecular complexation properties with [60]fullerene ("C-60"). T he X-ray structure of a (5)(2).C-60 clathrate was obtained and compared wit h the supramolecular complexation data obtained by a H-1 NMR study of 4 and 5 with C-60 in benzene-d(6), and toluene-d(8).