Si. Kimura et al., Temperature dependence of low-energy optical conductivity of Yb-4(As1-xPx)(3) (x=0, 0.05, 0.15), J PHYS JPN, 70(10), 2001, pp. 2829-2832
To investigate the anomalous transport property and the electronic structur
e near the Fermi level of Yb4As3, we measured the temperature dependence of
the reflectivity spectra of Yb-4(As1-xPx)(3) (x = 0, 0.05, 0.15) in the ph
oton energy range of 2 meV-1.5 eV. The optical conductivity spectrum due to
carrier absorption (Drude curve) significantly changes with temperature. A
bove 200 K, the Drude curve with a high effective carrier density (N-eff) a
nd a short relaxation time (tau) is commonly observed in all Yb-4(As1-xPx)(
3). On the other hand, below 70 K, the Drude curve changes to one with a lo
w N-eff and a long tau below 10 meV. At the same temperature, a new peak ap
pears at 15 meV in Yb4As3. The Drude curve and the new peak are considered
to originate from the bare As 4p hole band and the hybridization state betw
een the 4f and 5d bands on the Yb3+ chain, respectively.