Kn. Altmann et R. Reininger, DENSITY-DEPENDENCE OF THE CONDUCTION-BAND MINIMUM IN FLUID KRYPTON AND XENON FROM FIELD-IONIZATION OF (CH3)(2)S, The Journal of chemical physics, 107(6), 1997, pp. 1759-1764
The ionization potential distribution of (CH3)(2)S doped in fluid kryp
ton and xenon has been determined by means of field ionization in wide
density ranges. These distributions are simulated by convoluting the
field spectrum of pure (CH3)(2)S With the calculated polarization ener
gy distribution of the dopant ion in the media. The density dependence
of the conduction-band energy of excess electrons (V-0) in the fluids
is obtained from the energy shift between the experimental and simula
ted spectra. The resulting V-0 values are compared with previous exper
imental results and several theoretical calculations. (C) 1997 America
n Institute of Physics.