Y. Matsunaga et al., Nematic-isotropic transition temperature and dipole-dipole interaction. 4-X-substituted phenyl 4-(4-Y-substituted benzylideneamino)-benzoates, MOLEC CRYST, 363, 2001, pp. 51-60
The nematic-isotropic transition temperature of 4-X-phenyl 4-(4-Y-benzylide
neamino)benzoates, where the terminal groups X and Y are CN, CH3O, NO2, Cl,
Br, N (CH3)(2), CH3, F, or CF3, was examined. The transition temperature d
ifference between the two series, in which X or Y=CH3O and F, respectively,
decreases in this order: CF3 > NO2 > Cl = Br = F > CN > CH3 > CH3O > N (CH
3)(2). Thus, the groups are almost in the order of substituent constants ex
cept for the CN group, suggesting that the dipole-dipole interaction contri
butes significantly to the nematic thermal stability and also that the effe
ctive dipole moment of the molecule bearing CN and CH3O groups is markedly
reduced in the mesophase from that of the free molecule because of the anti
-parallel molecular association.