Citation
Tw. Lee et Ej. Corey, (2-methoxyphenyl)dimethylsilyl lithium and cuprate reagents offer unique advantages in multistep synthesis, ORG LETT, 3(21), 2001, pp. 3337-3339
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060
→ ACNP
Volume
3
Issue
21
Year of publication
2001
Pages
3337 - 3339
Database
ISI
SICI code
1523-7060(20011018)3:21<3337:(LACRO>2.0.ZU;2-U
Abstract
[GRAPHICS]
The new silyllithium reagent 1 and the corresponding cyanocuprate 3 are rea
dily generated under optimal conditions and are useful for the formation of
C-Si bonds. Tamao-Fleming oxidation of such C-Si bonds can be effected und
er very mild conditions.