The degradation behavior of polycrystalline MgB2 superconductor, exposed to
water and ambient atmosphere, has been studied. We have found that prolong
ed exposure to water completely destroys superconductivity. Optical microsc
opic and X-ray diffraction analyses indicate that, on exposure to water, th
e material becomes amorphous like. X-ray photoelectron spectroscopic measur
ements reveal the strongly hygroscopic character of MgB2 and we have found
that, even at room temperature, water and air change it into Mg(OH)(2), MgC
O3 and B2O3. (C) 2001 Elsevier Science B.V. All rights reserved.