This work reports two different ways of study providing potentially importa
nt information about nanoparticle films. The first study is about conductan
ce noise in PbS nanoparticle films. Monocrystalline and single-sized PbS na
noparticles are synthesized via the gas-phase and deposited electrostatical
ly onto semiconducting (GaAs) and on isolating (SiNx) substrates with plana
r electrode contacts. Low frequency current noise of one monolayer thick fi
lms are measured at various voltages, exhibiting diffusion noise characteri
stics, which indicates a random walk (diffusion) phenomenon of electrons be
tween the particles. In the second part of the paper, a new method is propo
sed which would be is able to predict the particle size of conductive nanop
article films in situ, during deposition. The method could be used for the
measurement of the time-derivative of conductance fluctuations during depos
ition. (C) 2001 Published by Elsevier Science B.V.