Synthesis, crystal structure, and IR absorption spectra of the adduct of copper(II) acetate monohydrate with 1-amino-4-aza-9-fluorenone Cu-2(CH3COO)(4)(H2O)(2) center dot C12H8N2O

Authors
Kuz'mina, NE Palkina, KK Polyakova, NV Strashnova, SB Koval'chukova, OV Zaitsev, BE Levov, AN
Citation
Ne. Kuz'Mina et al., Synthesis, crystal structure, and IR absorption spectra of the adduct of copper(II) acetate monohydrate with 1-amino-4-aza-9-fluorenone Cu-2(CH3COO)(4)(H2O)(2) center dot C12H8N2O, RUSS J C CH, 27(10), 2001, pp. 711-716
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
27
Issue
10
Year of publication
2001
Pages
711 - 716
Database
ISI
SICI code
1070-3284(200110)27:10<711:SCSAIA>2.0.ZU;2-H
Abstract
The crystal structure of the adduct of copper(II) acetate monohydrate and 1 -amino-4-aza-9-fluorenone Cu-2(CH3COO)(4)(H2O)(2) . C12H8N2O was determined . The structure is layered; the layers are formed by alternating columns of copper(II) aetate monohydrate complexes and columns of dimers of 1-amino-4 -aza-9-fluorenone. The layered structure of the adduct is stabilized by a h ydrogen bonding system. Changes in the IR absorption spectra due to the for mation of the adduct were discussed.