Experiment of the molecular deposition (MID) films with and without alkyl t
erminal deposited on the silicon wafer were conducted by using nanoindentat
ion. It was found that MID films and alkyl terminated MID films exhibit hig
her critical load (scratch resistance or adhesive strength) and lower coeff
icient of friction compared with the silicon substrate. Critical load (scra
tch resistance) increases with the number of layers, and coefficients of fr
iction of those MID film with alkyl terminal are still best for the same la
yer of MD film.