The synthesis of NaA zeolite membrane on a porous alpha -Al2O3 support by m
icrowave heating (MH) was investigated. The formation of a NaA zeolite memb
rane was drastically promoted by MH. The synthesis time was reduced from 3
h for conventional heating (CH) to 15 min for MH. Surface seeding cannot on
ly promote the formation of NaA zeolite on the support, but also inhibit th
e transformation of NaA zeolite into other types of zeolites. The thickness
of the NaA zeolite membrane synthesized by MH was about 4 mum, thinner tha
n that of NaA zeolite membrane synthesized by CH. The permeance of NaA zeol
ite membrane synthesized by MH was four times higher than that of the NaA z
eolite membrane synthesized by CH, while their permselectivities were compa
rable. Multi-stage synthesis resulted in the transformation of NaA zeolite
into other types of zeolites, and the perfection of the as-synthesized memb
rane decreased.
The formation mechanism of NaA zeolite membrane on the porous alpha -Al2O3
support by MH was proposed. The promotion effect on the formation of NaA ze
olite membrane by MH can be divided into two parts: the "thermal effect" an
d the "microwave effect". The formation of a homogeneous and thin NaA zeoli
te membrane resulted from both the "thermal effect" and the "microwave effe
ct", while the fast formation of NaA zeolite membrane was mainly caused by
the "microwave effect". (C) 2001 Elsevier Science B.V. All rights reserved.