N. Pic et al., Determination of the electrical properties of ultrathin silicon-based dielectric films: thermally grown SiNx, SOL ST ELEC, 45(8), 2001, pp. 1265-1270
The aim of this work is to obtain the electrical properties of a leaky 2 nm
ultrathin thermally grown nitride film using the classical high frequency
capacitance (C(V)) measurements, The substrate Si(100) surface cleaned in u
ltrahigh vacuum is nitrided in a low pressure (1 x 10(-4) mbar) of nitric o
xide (NO) gas at 1050 degreesC. This film is characterised by Auger electro
n spectroscopy, Fourier transform infrared spectroscopy, transmission elect
ron microscopy and reflection electron energy loss spectroscopy. The deposi
tion of a self-assembled insulating monolayer of organic molecules (octadec
yltrichlorosilane) on the nitride gives rise to a metal insulator semicondu
ctor structure which permits to obtain the electrical properties of the ult
rathin nitride film. (C) 2001 Elsevier Science Ltd. All rights reserved.