STABILIZATION OF THE TL2BA2CA2CU3O10 SUPERCONDUCTOR BY HG DOPING

Citation
Yx. Jia et al., STABILIZATION OF THE TL2BA2CA2CU3O10 SUPERCONDUCTOR BY HG DOPING, Physica. C, Superconductivity, 234(1-2), 1994, pp. 24-28
Citations number
8
Categorie Soggetti
Physics, Applied
ISSN journal
09214534
Volume
234
Issue
1-2
Year of publication
1994
Pages
24 - 28
Database
ISI
SICI code
0921-4534(1994)234:1-2<24:SOTTSB>2.0.ZU;2-4
Abstract
Hg doping of the triple-CuO2 layer oxide superconductor T2-xHgxBa2Ca2C u3O10 (Tl-2223) is investigated. Modest substitution of Hg2+ ions for Tl3+ ions leads to the stabilization of the Tl-2223 structure and an a pparently optimized superconducting onset temperature T-c=130 K. The s ituation is reminiscent of partial Bi ions replacement by Pb ions in t he lower-T-c Bi based oxide superconductors. Overdoping with Hg in Tl- 2223 leads again to a decrease in T-c.