A new type copper(II)-gadolinium(III) complex of phenol-based side-off type dinucleating ligand containing fully saturated amino nitrogens as coordinating atoms

Authors
Manseki, K Sakiyama, H Sakamoto, M Nishida, Y Aono, H Sadaoka, Y Ohba, M Okawa, H
Citation
K. Manseki et al., A new type copper(II)-gadolinium(III) complex of phenol-based side-off type dinucleating ligand containing fully saturated amino nitrogens as coordinating atoms, SYN REAC IN, 31(8), 2001, pp. 1443-1451
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
31
Issue
8
Year of publication
2001
Pages
1443 - 1451
Database
ISI
SICI code
0094-5714(200109)31:8<1443:ANTCCO>2.0.ZU;2-U
Abstract
The copper(II)-gadolinium(III) complex of a phenol-based side-off type di-n ucleating ligand was newly synthesized, using N, N'-dimethyl-N,N'-ethylene- di(5-bromo-3-formyl-2-hydroxybenzylamine). Structural analysis revealed tha t one of the two formyl groups is converted into a hemiacetal group and the two dinuclear CuGd units are bridged by the alcoholic oxygens of acetal gr oups of each unit to construct the tetranuclear (CuGd)(2) core.