Synthesis of aryl(or benzyl)-(Z)-N-[2-amino-1,2-dicyanovinyl]formamidines

Citation
A. Yahya-zadeh et Bl. Booth, Synthesis of aryl(or benzyl)-(Z)-N-[2-amino-1,2-dicyanovinyl]formamidines, SYN COMMUN, 31(23), 2001, pp. 3617-3622
Citations number
9
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
23
Year of publication
2001
Pages
3617 - 3622
Database
ISI
SICI code
0039-7911(2001)31:23<3617:SOAB>2.0.ZU;2-R
Abstract
Starting from readily available ethyl(Z)-N-(2-amino-1,2-dicyanovinyl)formim idate (1), the N-aryl (or benzyl)-N'-(2-amino-1,2-dicyanovinyl)formamidines (2) can be prepared in good yields by reaction with aromatic amines at roo m temperature in the presence of a catalytic amount of anilinium hydrochlor ide.