Cleavage of vinyl carbon-silicon bond in gamma-trimethylsilyl allylic alcohols

Authors
Al-Hassan, MI Miller, RB
Citation
Mi. Al-hassan et Rb. Miller, Cleavage of vinyl carbon-silicon bond in gamma-trimethylsilyl allylic alcohols, SYN COMMUN, 31(23), 2001, pp. 3641-3645
Citations number
6
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
23
Year of publication
2001
Pages
3641 - 3645
Database
ISI
SICI code
0039-7911(2001)31:23<3641:COVCBI>2.0.ZU;2-P
Abstract
Cleavage of the vinyl carbon silicon bond by fluoride ion requires a free h ydroxyl group located in such a position that stable cyclic transition stat e can be attained.