Peculiar steroidal saponins with opened E-ring from Solanum genera plants

Citation
Xh. Zhu et al., Peculiar steroidal saponins with opened E-ring from Solanum genera plants, TETRAHEDR L, 42(45), 2001, pp. 8043-8046
Citations number
8
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
45
Year of publication
2001
Pages
8043 - 8046
Database
ISI
SICI code
0040-4039(20011105)42:45<8043:PSSWOE>2.0.ZU;2-4
Abstract
Peculiar novel steroidal saponins with E-ring opened skeleton, a cholesten- 3 beta ,16.22,26-tetraol 3,26-di-O-glycoside corresponding to the precursor of the spirostanol and furostanol. a 16,22-dicarbonyl type steroid and a 2 0-22 seco-type steroid have been obtained from some Solanum genera plants. The occurrence of their unusual compounds would propose new important bioge netic routes for steroidal glycosides. (C) 2001 Elsevier Science Ltd. All r ights reserved.