Synthesis of optically active functionalised cyclic ketimines and their application in enantioselective catalysis

Authors
von Keyserlingk, NG Martens, J
Citation
Ng. Von Keyserlingk et J. Martens, Synthesis of optically active functionalised cyclic ketimines and their application in enantioselective catalysis, TETRAHEDR-A, 12(15), 2001, pp. 2213-2222
Citations number
29
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
12
Issue
15
Year of publication
2001
Pages
2213 - 2222
Database
ISI
SICI code
0957-4166(20010829)12:15<2213:SOOAFC>2.0.ZU;2-8
Abstract
The synthesis of enantiomerically pure cyclic ketimines attached to moietie s containing additional donor atoms is described. The resulting optically a ctive chelating ligands are tested in the rhodium-catalysed enantioselectiv e hydrosilylation of acetophenone with respect to their inductive potential . (C) 2001 Elsevier Science Ltd. All rights reserved.