Heterobimetallic complexes of lithium, aluminum, and gold the N-[2-N ',N '-(dimethylaminoethyl)-N-methyl-aminoethyl]-ferrocenyl ligand (eta(5)-C5H5)Fe{eta(5)-C5H3[CH(CH3)N(CH3)CH2CH2NMe2]-2}

Authors
Voigt, F Fischer, A Pietzsch, C Jacob, K
Citation
F. Voigt et al., Heterobimetallic complexes of lithium, aluminum, and gold the N-[2-N ',N '-(dimethylaminoethyl)-N-methyl-aminoethyl]-ferrocenyl ligand (eta(5)-C5H5)Fe{eta(5)-C5H3[CH(CH3)N(CH3)CH2CH2NMe2]-2}, Z ANORG A C, 627(10), 2001, pp. 2337-2343
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
10
Year of publication
2001
Pages
2337 - 2343
Database
ISI
SICI code
0044-2313(200110)627:10<2337:HCOLAA>2.0.ZU;2-F
Abstract
N-[2-N ' ,N '-(dimethylaminoethyl)-N-methyl-aminoethyl]ferrocene FcN,NH (1) reacts with (BuLi)-Bu-n under formation of the lithium organyl (FcN,N)Li ( 2). At reactions of 2 with AlBr3 and AuCl (.) PPh3 the heterobimetallic org ano derivatives (FcN,N)AlBr2 (3), (FcN,N)Au (.) PPh3 (4) are formed. A deta iled characterization of 2-4 was carried out by single crystal x-ray analys es as well as by NMR and Mo beta bauer spectroscopy.