Synthesis and crystal structure of [bis(N-oxo-2-acetylpyridine N-4-methylthiosemicarbazone)zinc(II)] monohydrate

Authors
Castineiras, A Dominguez, R Bordinhao, J de Oliveira, JS Bortoluzzi, AJ Horner, M
Citation
A. Castineiras et al., Synthesis and crystal structure of [bis(N-oxo-2-acetylpyridine N-4-methylthiosemicarbazone)zinc(II)] monohydrate, Z NATURFO B, 56(9), 2001, pp. 927-930
Citations number
14
Categorie Soggetti
Chemistry
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
ISSN journal
09320776 → ACNP
Volume
56
Issue
9
Year of publication
2001
Pages
927 - 930
Database
ISI
SICI code
0932-0776(200109)56:9<927:SACSO[>2.0.ZU;2-T
Abstract
The reaction of zinc(H) acetate dihydrate and the tetra-dentate N-Oxo-2-ace tylpyridine N-4-methylthiosemicarbazone (H4MLO) produces the novel complex [Zn(C9H11N4OS)(2).H2O] (1). The complex crystallizes in the orthorhombic sp ace group Pbca with a = 15.871(3), b = 16.890(3), c = 17.189(3) Angstrom, V = 4608(1) Angstrom (3), Z = 8. The Zn(II) ion is tetra-coordinated via the thiolate sulfur atom and the azomethine nitrogen atom of two deprotonated l igands. In the solid state, 1 is polymerized via hydrogen bonds with a wate r molecule of crystallization.