Electrochemical synthesis and a redetermination of Ni(acac)(2)(H2O)(2) center dot H2O

Authors
Zhou, XF Han, AJ Chu, DB Huang, ZX
Citation
Xf. Zhou et al., Electrochemical synthesis and a redetermination of Ni(acac)(2)(H2O)(2) center dot H2O, ACT CRYST E, 57, 2001, pp. M506-M508
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
11
Pages
M506 - M508
Database
ISI
SICI code
1600-5368(200111)57:<M506:ESAARO>2.0.ZU;2-P
Abstract
The title complex, bis(acetylacetonato)diaquanickel(II) monohydrate, [Ni(C5 H7O2)(2)(H2O)2)].H2O, was easily synthesized in high yield by electrochemic al dissolution of nickel metal in an acetylacetone and ethanol solution via direct hydrolysis of the electrolyte solution at a temperature of 333 K. T he crystal structure shows octahedral coordination of nickel with two trans aqua ligands. An uncoordinated water molecule engages in hydrogen bonding.