Synthesis and chemistry of the 16-electron osmium complex [OsBr(eta(5)-C5Me5)(PiPr(3))]

Authors
Glaser, PB Tilley, TD
Citation
Pb. Glaser et Td. Tilley, Synthesis and chemistry of the 16-electron osmium complex [OsBr(eta(5)-C5Me5)(PiPr(3))], EUR J INORG, (11), 2001, pp. 2747-2750
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
11
Year of publication
2001
Pages
2747 - 2750
Database
ISI
SICI code
1434-1948(200111):11<2747:SACOT1>2.0.ZU;2-6
Abstract
The isolable 16-electron half-sandwich Cls complex [OsBr(eta (C5Me5)-C-5)(P iPr(3))] has been synthesized and structurally characterized. This unsatura ted complex binds N-2 reversibly at low temperature as determined by IR and multinuclear NMR spectroscopy. The reactions of the title complex with CO, H-2, PhSiH3, and its thermolysis in C6H6 are reported.