Multifunctional polymers can play multi-roles such as laser light sour
ce, passive interconnects, optical signal processing and optical data
storage in the development of photonics technology. In this paper, two
approaches to achieve nanostructure control to introduce multifunctio
nality at both molecular and bulk levels are presented. A novel concep
t of multiphasic nanostructured composites is discussed. Various appli
cations of a specific multifunctional property introduced by strong tw
o-photon absorption and efficient fluorescence are presented. The comb
ined action of these two functions produces upconverted emission. Spec
ific applications discussed are upconversion lasing, optical data stor
age, confocal microscopy, and photodynamic therapy.