A new type of membrane with potential-controllable functions was prepared b
y grafting polyaniline to the surface of track-etch Nucleopore membrane wit
h a vacuum deposited gold layer (PANI-membranes). Because of the cylindrica
l shape of these pores, a nanocylinder of the desired conducting material i
s obtained in each pore. A potential applied to PANI-membranes governs the
properties of the conducting layer, such as charge and its distribution, co
nformation, and density and, hence, controls the diffusion rate of substanc
es through these membranes. The variation in diffusion rates of different s
ubstances with different potentials applied to PANI-membranes provides the
basis for the application of these membranes in separation processes and se
nsors.