Five glycoalkaloids were identified from the aerial parts of wild Sola
num commersonii Dun. ex Poir growing in Uruguay and their structures e
lucidated mainly by chemical and spectroscopic methods. In addition to
the already known commersonine, demissine, tomarine and dehydrocommer
sonine, a new glycoalkaloid, identified as Delta(5)-demissine, a-D-Xyl
p-(1-->3)]-beta-D-Glcp-(1-->4)-beta-D-Galp} was found. Tomatine and de
hydrocommersonine have not been reported earlier as components of this
plant. The glycoalkaloid composition found in the wild plants studied
differ significatively from those described earlier, and have some im
plications in taxonomy and its use in potato breeding.