Citation
C. Kotowicz et al., Absolute configuration of trixanolides from Trixis pallida, J NAT PROD, 64(10), 2001, pp. 1326-1331
Citations number
12
Categorie Soggetti
Agricultural Chemistry","Pharmacology & Toxicology
Journal title
JOURNAL OF NATURAL PRODUCTS
ISSN journal
01633864
→ ACNP
Volume
64
Issue
10
Year of publication
2001
Pages
1326 - 1331
Database
ISI
SICI code
0163-3864(200110)64:10<1326:ACOTFT>2.0.ZU;2-X
Abstract
The aerial parts of Trixis pallida afforded seven known trixanolides (18-24
) together with 17 new trixanolides (1-17). Their structures were determine
d by 1D and 2D NMR techniques, while the absolute configuration of the trix
ane skeleton was determined using the Mosher method and turned out to be en
antiomeric to that reported using the Horeau method. This result is further
discussed from the biosynthetic point of view.