Citation
Tr. Van Den Ancker et al., Syntheses and crystal structures of binuclear gold(I), silver(I) and copper(I) complexes containing bulky pyridyl functionalised alkyl ligands, J CHEM S DA, (20), 2001, pp. 3069-3072
Citations number
32
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773
→ ACNP
Issue
20
Year of publication
2001
Pages
3069 - 3072
Database
ISI
SICI code
1472-7773(2001):20<3069:SACSOB>2.0.ZU;2-R
Abstract
Treatment of (CO) AuCl, CuCl or AgNO3 with 2-LiC(SiMe3)(2)-Py-6-CH2R gives
the binuclear metal compounds [M-2(mu -2-C(SiMe3)(2)-6-CH2RPy)(2)] [R = H,
M = Au (1), Cu (2) and Ag (3); R = Me3Si, M = Cu (4)]. The dimeric structur
es of complexes 1, 2 and 4 have been established by single-crystal X-ray di
ffraction studies. The complexes are centrosymmetric with each ligand bridg
ing the two metal centres which are in close proximity to each other [M . .
.M 2.690(2) Angstrom in 1, 2.436(1) Angstrom in 2 and 2.431(1) Angstrom in
4].