Citation
J. Shailaja et al., Use of a confined space (zeolite) in enantio- and diastereo-selective photoreactions, MICROP M M, 48(1-3), 2001, pp. 319-328
Citations number
20
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
MICROPOROUS AND MESOPOROUS MATERIALS
ISSN journal
13871811
→ ACNP
Volume
48
Issue
1-3
Year of publication
2001
Pages
319 - 328
Database
ISI
SICI code
1387-1811(20011101)48:1-3<319:UOACS(>2.0.ZU;2-C
Abstract
The confined spaces of zeolites have been found to be ideal for carrying ou
t enantio- and diastereo-selective photoreactions. Four methods, (chiral in
ductor, chiral auxiliary, a combination (chiral inductor + chiral auxiliary
) and chiral inductor as a reagent) have been explored and all were found t
o give reasonable chiral induction on several systems. The uniqueness of ze
olites as media although established in this study, the factors that contro
l the high chiral induction in zeolite with respect to solution are yet to
be established. (C) 2001 Elsevier Science B.V. All rights reserved.