Holographic gratings were formed by using crosslinked polymer-liquid crysta
l composites containing azobenzenes. The holographic recording was based on
photoinduced alignment of a nematic liquid crystal filled in a cell as a r
esult of the amplification of photoreorientation of azobenzene residues and
exhibited volume holographic properties with Bragg diffraction. Spatial fr
equency of 1 mum was obtained for a cell of 200 mum in thickness. whereas d
iffraction efficiencies depended on holographic exposure doses and cell thi
ckness. A free-standing film of this composite system was also prepared to
perform holographic recording.