The present work deals with synthesis of two homologous series possessing,
ester and amide linkage and a large lateral aryl substituent. The large lat
eral group is attached to the main molecule through an amide linkage. Mesog
enic amides are rare even when the amide linkage is present in the main mol
ecular framework. However, in the present work the compounds containing ami
de linkage in lateral moiety also exhibit mesophases of high thermal stabil
ity.