Gk. Johri et al., Experimental study of dielectric relaxation in 4-cyano-4-n-hexyl biphenyl nematic liquid crystal, MOLEC CRYST, 367, 2001, pp. 3499-3505
Microwave cavity spectrometer has been used to measure the width of resonan
t profile and the shift of the resonant frequency. The observed data are an
alyzed to determine permittivity, dielectric loss and relaxation time. The
relative variation of dielectric loss and permittivity at different tempera
tures has been studied for the purpose to monitor the phase changes in the
range 282 degrees K to 314 degrees K and to identify the transition tempera
tures. We have used two frequencies 9.0 GHz and 29.867 GHz to see the frequ
ency dependence for the purpose to compare relaxation mechanism. The techni
que used is useful as it needs if small quantity (< 0.001 cm(3)) of the sam
ple and provides fruitful information about the macroscopic structure of th
e liquid crystal. The transition temperatures are TC -->N = 287.6 degrees K
and TN -->I = 301.9 degrees K.