New series of ferroelectric liquid crystalline materials containing methyl
and methoxy lateral groups on the aromatic ring of the core unit, as well a
s non-substituted materials have been synthesised. All compounds exhibit a
wide temperature range of the ferroelectric chiral SmC* phase. A low temper
ature ferroelectric phase was detected for some of the investigated compoun
ds probably composed of the SmC* phase and a crystalline phase. Measurement
s of spontaneous polarisation and tilt angle, helical pitch and dielectric
permittivity has been performed.